Synthesis and Structure of Di(2-phenyl-8-quinolyl) Diselenide and Zinc bis[(2-phenyl-8-quinolyl)selenolate]

Химия гетероциклических соединений 2011
E. Silins, Sergejs Beļakovs, J. Ašaks, A. Tokmanovs, L. Pecs, D. Zaruma

Di(2-phenyl-8-quinolyl) diselenide [2-(C6H5)C9H5NSe]2 and zinc bis[(2-phenyl-9-quinolyl)selenolate], Zn [2-(C6H5)C9H5NSe]2, have been synthesized. The molecular and crystal structure of the compounds were determined by X-ray structural analysis. The structures of the 2-phenyl-8-quinolylselenol ligand in the molecules of di(2-phenyl-8-quinolyl) diselenide and in the intracomplex compound of zinc are compared. The effect of the phenyl group in position 2 of the quinoline nucleus on the formation of the molecules and their packing in the crystal structure is discussed.

Keywords
intracomplex compounds of (2-phenyl-8-quinolyl)selenolates; di(2-phenyl-8-quinolyl)diselenide; zinc complexes; molecular and crystal structure
Hyperlink
http://hgs.osi.lv/index.php/hgs/article/view/2100

Silins, E., Beļakovs, S., Ašaks, J., Tokmanovs, A., Pecs, L., Zaruma, D. Synthesis and Structure of Di(2-phenyl-8-quinolyl) Diselenide and Zinc bis[(2-phenyl-8-quinolyl)selenolate]. Химия гетероциклических соединений, 2011, No. 3, pp.371-378. ISSN 0132-6244.

Publication language
Russian (ru)