Iodonium Salts Are Key Intermediates in Pd-Catalyzed Acetoxylation of Pyrroles

ChemInform 2011
Dmitrijs Lubriks, D. Sokolovs, Edgars Sūna

The reaction of pyrroles and indoles with Ph-I(O-Ac)2 proceeds via initial regioselective formation of iodonium acetate intermediates which are converted into acetoxy derivatives.

Keywords
pyrrole derivatives; oxidation, dehydrogenation; halogenation; indole derivatives, isoindole derivatives
DOI
10.1002/chin.201152100
Hyperlink
http://dx.doi.org/10.1002/chin.201152100

Lubriks, D., Sokolovs, D., Sūna, E. Iodonium Salts Are Key Intermediates in Pd-Catalyzed Acetoxylation of Pyrroles. ChemInform, 2011, Vol.42, Iss.52, pp.100-100. ISSN 1522-2667. Available from: doi:10.1002/chin.201152100

Publication language
English (en)