Herein, we present the synthesis and spectroscopic studies of the furanose-based amide- and triazole-linked carbopeptoids. Acetonide protected furanose rings are stereochemically defined molecular scaffolds that impose certain rigidity to the oligomeric structures made from them. Linking with an amide linkage provides open sites for the formation of intramolecular hydrogen bonds when incorporated in the larger molecules, while triazole linkers add conformational stability and rigidity.