Synthesis and Applications of Silyl 2-Methylprop-2-ene-1-sulfinates in Preparative Silylation and GC-Derivatization Reactions of Polyols and Carbohydrates
ChemInform 2016
Dean Markovic, Wandji Augustin Tchawou, Irina Novosjolova, Sylvain Laclef, Dmitrijs Stepanovs, Māris Turks, Pierre Vogel

Trimethylsilyl, triethylsilyl, tert-butyldimethylsilyl, and triisopropylsilyl 2-methylprop-2-ene-1-sulfinates are prepared by Cu-catalyzed sila-ene reactions of methallylsilanes with SO2.


Keywords
silyl 2-methylprop-2-ene-1-sulfinates, Cu-catalyzed sila-ene reaction, methallylsilanes, SO2.
DOI
10.1002/chin.201631209

Markovic, D., Tchawou, W., Novosjolova, I., Laclef, S., Stepanovs, D., Turks, M., Vogel, P. Synthesis and Applications of Silyl 2-Methylprop-2-ene-1-sulfinates in Preparative Silylation and GC-Derivatization Reactions of Polyols and Carbohydrates. ChemInform, 2016, Vol.47, Iss.31, pp.1-1. e-ISSN 1522-2667. Available from: doi:10.1002/chin.201631209

Publication language
English (en)
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