Para-Selective Cu-Catalyzed C—H Aryloxylation of Electron-Rich Arenes and Heteroarenes

ChemInform 2016
Igors Sokolovs, Edgars Sūna

Reaction of electron rich arenes (I) and (IV), and electron rich heterocycles (VI) with hypervalent iodine reagent generates λ3-iodane intermediates, which readily undergo Cu-catalyzed reaction with a variety of phenols to form diaryl ethers.

DOI
10.1002/chin.201623089

Sokolovs, I., Sūna, E. Para-Selective Cu-Catalyzed C—H Aryloxylation of Electron-Rich Arenes and Heteroarenes. ChemInform, 2016, Vol.47, Iss.23, pp.1-1. e-ISSN 1522-2667. Available from: doi:10.1002/chin.201623089

Publication language
English (en)