Cationic 1,2-Silyl Shift in Propargyl Silanes

21st European Symposium on Organic Chemistry Poster Abstracts 2019
Mikus Puriņš, Māris Turks

Transformations involving non-vertical stabilization type 1,2-silyl shift in propargyl silanes give access to multi-functionalized products containing useful alkenyl silane moiety. Apart from the early reports of Danheiser [1] and Evans [2], this approach is still largely underdeveloped.

Keywords
Propargyl silanes, Bronsted Acid, electrophile nucleophile pair

Puriņš, M., Turks, M. Cationic 1,2-Silyl Shift in Propargyl Silanes. In: 21st European Symposium on Organic Chemistry Poster Abstracts, Austria, Vienna, 14-18 July, 2019. Vienna: 2019, pp.485-485.

Publication language
English (en)