Heterocyclization of Terminally Functionalized Propargyl Silanes via 1,2-Silyl Shift

Balticum Organicum Syntheticum: Program and Abstract Book 2022
Rasma Kroņkalne, Artjoms Ubaidullajevs, Rūdolfs Beļaunieks, Māris Turks

In this work we investigate the 1,2-silyl shift in propargyl silanes containing intramolecular O-, N- or S-nucleophile and subsequent cyclization as a novel synthesis pathway towards 2-(1-trialkylsilyl) vinyl-substituted heterocycles.

Keywords
1,2-Silyl Shift, Propargyl Silanes, Heterocyclization

Kroņkalne, R., Ubaidullajevs, A., Beļaunieks, R., Turks, M. Heterocyclization of Terminally Functionalized Propargyl Silanes via 1,2-Silyl Shift. In: Balticum Organicum Syntheticum: Program and Abstract Book, Lithuania, Vilnius, 3-6 July, 2022. Vilnius: UAB Kalanis, 2022, pp.104-104. ISBN 978-609-96039-4-0. e-ISBN 978-609-96039-3-3.

Publication language
English (en)