Free-space optics (FSO) in the mid-infrared (mid-IR) contains rich spectral resources for future ultrahigh-speed wireless communications yet is currently under-exploited. Two atmospheric transmission windows at the mid-IR, namely, the mid-wave IR (MWIR, 3-5 μm) and the long-wave IR (LWIR, 8-12 μm), show great potential in supporting free-space communications for both terrestrial and space application scenarios. Particularly, the LWIR signal with a longer wavelength has high intrinsic robustness against aerosols' scattering and turbulence-induced scintillation and beam broadening effects, which are the main concerns hindering the wide deployment of practical FSO systems. In this context, high-bandwidth semiconductor-based mid-IR FSO transceivers will be desirable to meet the requirements of low energy consumption and small footprints for large-volume development and deployment. Quantum cascade devices, including quantum cascade lasers (QCLs) and quantum cascade detectors (QCDs), appear promising candidates to fulfill this role. In this work, we report a high-speed LWIR FSO transmission demonstration with a 9.6-μm directly-modulated (DM)-QCL and a fully passive QCD without any active cooling or bias voltage. Up to 8 Gb/s, 10 Gb/s, and 11 Gb/s signal transmissions are achieved when operating the DM-QCL at 10 °C, 5 °C, and 0 °C, respectively. These results indicate a significant step towards an envisioned fully-connected mid-IR FSO solution empowered by the quantum cascade semiconductor devices.