Harnessing the 1,2-Silyl Shift for the Syntheis of Functionalized Alkenes from Propargyl Silanes

2023
Rūdolfs Beļaunieks

Defending
13.10.2023. 14:00, Materiālzinātnes un lietišķās ķīmijas fakultāte, Paula Valdena ielā 3/7, 272.auditorijā

Supervisor
Māris Turks

Reviewers
Kaspars Traskovskis, Mark McLaughlin, Grzegorz Hreczycho

The Doctoral Thesis has been prepared as a collection of thematically related scientific publications complemened by summaries in Latvian and English. The Doctoral Thesis unites four scientific publications. Herein we have developed novel synthetic strategies for the electrophile-induced synthesis of functionalized alkenes from propargyl silanes. Developed methods allow to synthesize allyl-functionalized alkenes, heterocyclic derivatives, and sulfolenes. Obtained products have been demonstrated as useful synthetic building blocks for pharmaceutical or materials science industries.

Keywords
Propargilsilāni, alkēni, 1,2-sililnobīde
DOI
10.7250/9789934229640

Beļaunieks, Rūdolfs. Harnessing the 1,2-Silyl Shift for the Syntheis of Functionalized Alkenes from Propargyl Silanes. PhD Thesis. Rīga: [RTU], 2023. 75 p.

Publication language
Latvian (lv)