Allylic Amination via Acid Catalyzed Leaving Group Activation
Current Green Chemistry 2016
Marija Skvorcova, Aigars Jirgensons

Background: Allylic amination via acid catalyzed activation of a leaving group is promoted by non-expensive and low toxicity Lewis acid and Bronsted acid catalysts to give valuable allyl amine derivatives. In many cases, non-toxic byproducts such as water or acetic acid are generated. Moreover catalysts that perform the reactions in water as a solvent and the use of recyclable catalysts have been developed. Methods: Peer-reviewed research literature methods on allylic amination via acid catalyzed activation were compiled using data bases such as Sci-Finder and Scopus. Results: The mini-review summarizes the most important methods for allylic amination via acid catalyzed activation of a leaving group in the recent decade. These are divide in two main groups - Lewis acid and Bronsted acid catalysed reactions. Conclusion: Allylic amination via acid catalyzed activation of a leaving group meet criteria of the green chemistry paradigm which has motivated method development for this type of reaction in recent years.


Atslēgas vārdi
Allylic substitution, allylic amination, lewis acids, bronsted acids, green chemistry, allylic alcohols, carbenium ion.
DOI
10.2174/2213346103666160905101423
Hipersaite
http://www.eurekaselect.com/145339/article

Skvorcova, M., Jirgensons, A. Allylic Amination via Acid Catalyzed Leaving Group Activation. Current Green Chemistry, 2016, Vol. 3, No. 2, 145.-159.lpp. ISSN 2213-3461. e-ISSN 2213-347X. Pieejams: doi:10.2174/2213346103666160905101423

Publikācijas valoda
English (en)
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