Liquid Membrane System for Extraction and Electrodeposition of Lead(II) During Electrodialysis
Materials Science and Applied Chemistry 2017
Tatiana Sadyrbaeva

A novel method for lead(II) removal from aqueous acidic solutions is presented. The method involves electrodialysis through bulk liquid membranes accompanied by electrodeposition of metal from the cathodic solution. Solutions of di(2-ethylhexyl)phosphoric acid with admixtures of tri-n-octylamine in 1,2-dichloroethane were used as the liquid membranes. The effects of the main electrodialysis parameters as well as of the composition of the liquid membranes and aqueous solutions on the lead(II) transport rate are studied. The optimal conditions are determined. A possibility of effective single-stage transfer of lead(II) through the liquid membrane into dilute solutions of perchloric, nitric and acetic acids is demonstrated. Dense and adherent lead electrodeposits are obtained from perchloric acid solutions. Maximum extraction degree of 93 % and electrodeposition degree of ~60 % are obtained during 5 h of electrodialysis.


Atslēgas vārdi
Di(2-ethylhexyl)phosphoric acid, electrodeposition, electrodialysis, lead, liquid membrane, tri-n-octylamine
DOI
10.1515/msac-2017-0004

Sadyrbaeva, T. Liquid Membrane System for Extraction and Electrodeposition of Lead(II) During Electrodialysis. Materials Science and Applied Chemistry, 2017, 34, 29.-33.lpp. ISSN 1407-7353. e-ISSN 2255-8713. Pieejams: doi:10.1515/msac-2017-0004

Publikācijas valoda
English (en)
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