Synthesis of Cyclic N-Tosyliminocarbonates by Lewis Acid Catalyzed Allylic Substitution of Trichloroacetimidates

ChemInform 2013
Liene Grigorjeva, Aigars Jirgensons

The intramolecular Lewis acid catalyzed allylic substitution of the imidate group in N-tosylcarbamates gives N-tosyliminocarbonates with high trans-selectivity as major products.

Keywords
dioxole derivatives; ring closure reactions
DOI
10.1002/chin.201313100
Hyperlink
http://dx.doi.org/10.1002/chin.201313100

Grigorjeva, L., Jirgensons, A. Synthesis of Cyclic N-Tosyliminocarbonates by Lewis Acid Catalyzed Allylic Substitution of Trichloroacetimidates. ChemInform, 2013, Vol.44, Iss.13, pp.100-100. ISSN 1522-2667. Available from: doi:10.1002/chin.201313100

Publication language
English (en)