Tetrahydro-1,3-oxazepines via Intramolecular Amination of Cyclopropylmethyl Cation

ChemInform 2015
Marija Skvorcova, Liene Grigorjeva, Aigars Jirgensons

The transformation of cyclopropyl-group containing bis-imidates to cyclopropylmethyl cations followed by an intramolecular regioselective amination of the latter is described.

Keywords
multi-membered O,N,S-heterocycles (with at least 2 different heteroatoms);ring expansion;catalysis, phase-transfer catalysis;ring opening reactions
DOI
10.1002/chin.201544200
Hyperlink
http://onlinelibrary.wiley.com/doi/10.1002/chin.201544200/abstract

Skvorcova, M., Grigorjeva, L., Jirgensons, A. Tetrahydro-1,3-oxazepines via Intramolecular Amination of Cyclopropylmethyl Cation. ChemInform, 2015, Vol.46, Iss.44, pp.a-b. e-ISSN 1522-2667. Available from: doi:10.1002/chin.201544200

Publication language
English (en)