Application of Element Organic Compound-Derived Allylsulfinates in Organic Synthesis

Balticum Organicum Syntheticum: Program and Abstracts 2016
Agnese Stikute, Vilnis Peipiņš, Mikus Puriņš, Māris Turks

We have developed a novel approach to sulfoxide synthesis which is based on sila-ene reaction between allylsilanes and SO2 followed by LiCl- or ZnCl2-assisted Grignard reagent addition to the S-center of silyl sulfinate. The scope of the method has been demonstrated with the successful use of aryl-, alkyl, allyl- and heterocyclic Grignard reagents.

Atslēgas vārdi
Allylsilanes, Allylboranes, allylsilylsulfinates, sulfur dioxide
Hipersaite
http://www.boschem.eu/public/BOS2016/BOS-2016_Anstract-Book_Final.pdf

Stikute, A., Peipiņš, V., Puriņš, M., Turks, M. Application of Element Organic Compound-Derived Allylsulfinates in Organic Synthesis. No: Balticum Organicum Syntheticum: Program and Abstracts, Latvija, Rīga, 3.-6. jūlijs, 2016. Rīga: 2016, 153.-153.lpp.

Publikācijas valoda
English (en)