Liquid Sulfur Dioxide – Beneficial Solvent for Transformations Involving Carbenium Ion Intermediates

Latvijas Universitātes 77. starptautiskā zinātniskā konference. Ķīmijas sekcija: tēžu krājums 2019
Krista Gulbe, Kristaps Leškovskis

Due to its high polarity and Lewis acid properties liquid sulfur dioxide can be used as a strongly ionizing solvent. Consequently, it has promoting effect on various organic transformations that involve ionic intermediates. Herein we report application of liquid sulfur dioxide as a solvent for alkyne hydration and hydrohalogenation as well as nucleophilic ring opening of methylene cyclopropanes.

Atslēgas vārdi
sulfur dioxide, alkyne, hydration, hydrohalogenation, methylene cyclopropane

Suta, K., Leškovskis, K. Liquid Sulfur Dioxide – Beneficial Solvent for Transformations Involving Carbenium Ion Intermediates. No: Latvijas Universitātes 77. starptautiskā zinātniskā konference. Ķīmijas sekcija: tēžu krājums, Latvija, Rīga, 19.-19. februāris, 2019. Rīga: Latvijas Universitāte, 2019, 54.-54.lpp. ISBN 978-9934-18-399-7.

Publikācijas valoda
English (en)